Corrosion & Electrolysis

How to Protect Your Boating Investment

© Alan Sorum

Aug 12, 2006
There are two broad types of corrosion in vessels, galvanic corrosion and electrolysis. Boat owners can do a number of things to protect their floating investments.

Galvanic Corrosion

Galvanic corrosion occurs when two dissimilar metals form a natural battery when placed in contact with each other while immersed in an electrolyte. Seawater is a perfect electrolyte for metals. Metals vary in their reaction to being part of this natural battery. Metals that are more active are anodes or less noble. In a galvanic cell a less noble metal, like zinc, will dissolve sooner a more noble metal like brass. Prevention includes proper choices for metals used in vessel construction, use of protective paints and sacrificial anodes. Some suggestions to reduce corrosion on your boat can include:

  • Avoid using bottom paint that is incompatible with the vessel hull material. A good example is copper-based bottom paint on an aluminum hulled boat
  • Steel boats should not be moored directly next to aluminum vessels
  • Try to use fasteners on your boat made of similar metals throughout the vessel. Use all brass or all stainless steel for example

Electrolysis

Electrolysis is also the corrosion of dissimilar metals, but a different process causes it. A difference in the direct potential current that exists between two dissimilar metals is the reason for the problem. This is a stray current or circuit that is not following an anticipated path. Improper wiring, poor choices in building materials, or defective electrical appliances can cause it. Introduced currents will flow by the path of least resistance. Stray current can also cause Electric Shock Drowning.

Electrolysis is much more destructive to boats than galvanic corrosion. You can reduce electrolysis with these iteas:

  • Avoid the use of common automotive battery chargers on your boat. These chargers use an autotransformer in which the primary and secondary windings are electrically connected. Marine battery chargers use an isolation transformer. An isolation transformer has separate windings and does not allow current to pass into the vessel from the utility connection
  • Vessels using a positive ground electrical system should avoid mooring next to one with a negative ground system
  • Check the connections to any two bilge pumps that are electrically connected. Ensure that each pump shares the same positive and ground connection. If one pump is grounded to the frame and the second is not, a stray current will be introduced
  • Electric welders can introduce current into salt water due to frayed or damaged connectors. If welding is required on a vessel, it is better if the welder is mounted on the boat being welded
  • Check your vessel for reversed polarity
  • Check to see if any severe corrosion is present near telephone connections. Telephone service voltage can introduce 48 volts of current into the water
  • Install sacrificial zincs on your boat and properly maintain them
  • Keep a layer of quality bottom paint applied to all hull surfaces in contact with the water
  • Tilting your outboard motor out of the water may completely eliminate corrosion

One ideal solution for vessel owners is to purchase and install an isolation transformer for their vessel electrical system. Vessels moored along each other act like the plates within a battery. One boat can introduce current into the water and damage may not occur until it reaches a boat six spaces down. Using an isolation transfer effectively takes you out of the battery and protects the boat from introduced stray current.

Marinas should have a policy in place to address the proper use of shore power cords. Shore power cords need to be designed for use in the marine environment and UL approved. Don't use a common household extension cord for your boat! Marine power plugs and receptacles are built to standards set by the National Fire Protection Association. Using the wrong plug in the wrong receptacle or use of a worn fixture can cause fire and corrosion problems.

Corrosion can be caused by multiple factors. Items addressed in this article will give you a good start on preventing damage to your vessel. Talk to your harbormaster and boat mechanic about additional safeguards that may work for you.


The copyright of the article Corrosion & Electrolysis in Boating & Sailing is owned by Alan Sorum. Permission to republish Corrosion & Electrolysis in print or online must be granted by the author in writing.




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Comments
Jul 6, 2007 11:44 PM
Yen-ti :
I would like to have the following information: Which combination will produce least amount of electrolysis: brass and stainless steel,or nickel and stainless steel?
dragonfly44
Aug 11, 2007 5:16 PM
Alan Sorum :
Dragonfly44,

Sorry there hasn't been a faster response to your question. There was no title listed for your post, so it didn't show up in the list of current discussion topics.

The further two metals are apart on the galvanic series chart, the greater the potential current that can pass between them. The voltage range for 400 series stainless steel is -0.20 to -0.35, admirality brass is -0.25 to -0.34, and 90-10 copper nickel is -0.13 to -0.22. Using these three metals as examples, the nickel/stainless pairing would generate less corrosion. Brass is much further away on the scale. A note of caution, there are many different types of stainless steel, copper-nickel and brass or bronze used on boats. The best match will vary with the specific metal type used.

Thanks for the question.
2 Comments